Interactions between smectites and polyelectrolytes

Thesis book INTERACTIONS BETWEEN CATIONIC POLYELECTROLYTES AND ANIONIC SURFACTANTS

Effective Interactions Between Rigid Polyelectrolytes and Like-charged Planar Surfaces

We study the effective interaction between a planar array of uniformly negatively charged, stiff rods parallel to a negatively charged planar substrate in the absence of salt in a continuous, isotropic dielectric medium. Using Brownian dynamics simulations, we examine the general effects of counterion valence, rod spacing, macroion charge densities, and the rod size on the attractive rod-surfac...

Attractive interactions between rodlike polyelectrolytes: polarization, crystallization, and packing.

We study the attractive interactions between rodlike charged polymers in solution that appear in the presence of multivalence counterions. The counterions condensed to the rods exhibit both a strong transversal polarization and a longitudinal crystalline arrangement. At short distances between the rods, the fraction of condensed counterions increases, and the majority of these occupy the region...

Charge Interactions in Cylindrical Polyelectrolytes

The Debye-Huckel equation is solved for the electrostatic interaction of point charges on the surface of a dielectric cylinder immersed in salt water. Numerical results are given for the potential as a function of axial separation for charges on the same side and on opposite sides of the cylinder, and for two values of the Debye screening length: infinity and unity, in units of the cylinder rad...

Conformations and interactions of star-branched polyelectrolytes.

Combining monomer-resolved molecular dynamics simulations with a theory based on a variational free energy, we calculate the conformational properties and the effective interactions of star-branched polyelectrolytes for a large variety of arm numbers, degrees of polymerization, and charge fractions, with and without added salt. We find quantitative agreement between theory and simulation and pu...